Valencies of Positive and Negative Ions of Concentration Cell with Transference Solution

STEP 0: Pre-Calculation Summary
Formula Used
Valencies of Positive and Negative Ions = ((Transport Number of Anion*Total number of Ions*[R]*Temperature)/(EMF of Cell*Number of Positive and Negative Ions*[Faraday]))*ln(Cathodic Ionic Activity/Anodic Ionic Activity)
= ((t-*ν*[R]*T)/(EMF**[Faraday]))*ln(a2/a1)
This formula uses 2 Constants, 1 Functions, 8 Variables
Constants Used
[Faraday] - Faraday constant Value Taken As 96485.33212
[R] - Universal gas constant Value Taken As 8.31446261815324
Functions Used
ln - The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function., ln(Number)
Variables Used
Valencies of Positive and Negative Ions - The Valencies of positive and negative ions is the valency of electrolytes with respect to electrodes with which ions are reversible.
Transport Number of Anion - The Transport Number of Anion is ratio of current carried by anion to total current.
Total number of Ions - The Total number of ions is the number of ions present in the electrolytic solution.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
EMF of Cell - (Measured in Volt) - The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Number of Positive and Negative Ions - The Number of Positive and Negative Ions is the amount of cations and anions present in the electrolytic solution.
Cathodic Ionic Activity - (Measured in Mole per Kilogram) - Cathodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in a cathodic half-cell.
Anodic Ionic Activity - (Measured in Mole per Kilogram) - The Anodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in an anodic half cell.
STEP 1: Convert Input(s) to Base Unit
Transport Number of Anion: 49 --> No Conversion Required
Total number of Ions: 110 --> No Conversion Required
Temperature: 298 Kelvin --> 298 Kelvin No Conversion Required
EMF of Cell: 0.5 Volt --> 0.5 Volt No Conversion Required
Number of Positive and Negative Ions: 81.35 --> No Conversion Required
Cathodic Ionic Activity: 0.36 Mole per Kilogram --> 0.36 Mole per Kilogram No Conversion Required
Anodic Ionic Activity: 0.2 Mole per Kilogram --> 0.2 Mole per Kilogram No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
Z± = ((t-*ν*[R]*T)/(EMF*v±*[Faraday]))*ln(a2/a1) --> ((49*110*[R]*298)/(0.5*81.35*[Faraday]))*ln(0.36/0.2)
Evaluating ... ...
= 2.00018462966138
STEP 3: Convert Result to Output's Unit
2.00018462966138 --> No Conversion Required
FINAL ANSWER
2.00018462966138 2.000185 <-- Valencies of Positive and Negative Ions
(Calculation completed in 00.006 seconds)

Credits

Creator Image
Created by Prashant Singh
K J Somaiya College of science (K J Somaiya), Mumbai
Prashant Singh has created this Calculator and 700+ more calculators!
Verifier Image
Verified by Prerana Bakli
University of Hawaiʻi at Mānoa (UH Manoa), Hawaii, USA
Prerana Bakli has verified this Calculator and 1600+ more calculators!

Electrolytes and Ions Calculators

Time required for Flowing of Charge given Mass and Time
​ LaTeX ​ Go Total Time Taken = Mass of Ions/(Electrochemical Equivalent of Element*Electric Current)
Cell Potential given Electrochemical Work
​ LaTeX ​ Go Cell Potential = (Work Done/(Moles of Electron Transferred*[Faraday]))
Quantity of Charges given Mass of Substance
​ LaTeX ​ Go Charge = Mass of Ions/Electrochemical Equivalent of Element
Ionic Mobility
​ LaTeX ​ Go Ionic Mobility = Speed of Ions/Potential Gradient

Valencies of Positive and Negative Ions of Concentration Cell with Transference Formula

​LaTeX ​Go
Valencies of Positive and Negative Ions = ((Transport Number of Anion*Total number of Ions*[R]*Temperature)/(EMF of Cell*Number of Positive and Negative Ions*[Faraday]))*ln(Cathodic Ionic Activity/Anodic Ionic Activity)
= ((t-*ν*[R]*T)/(EMF**[Faraday]))*ln(a2/a1)

What is concentration cell with transference?

A cell in which the transference of a substance from a system of high concentration to one at low concentration results in the production of electrical energy is called a concentration cell. It consists of two half cells having two identical electrodes and identical electrolytes but with different concentrations. EMF of this cell depends upon the difference of concentration. In a concentration cell with transference, there is a direct transference of electrolytes. The same electrode is reversible with respect to one of the ions of the electrolyte.

How to Calculate Valencies of Positive and Negative Ions of Concentration Cell with Transference?

Valencies of Positive and Negative Ions of Concentration Cell with Transference calculator uses Valencies of Positive and Negative Ions = ((Transport Number of Anion*Total number of Ions*[R]*Temperature)/(EMF of Cell*Number of Positive and Negative Ions*[Faraday]))*ln(Cathodic Ionic Activity/Anodic Ionic Activity) to calculate the Valencies of Positive and Negative Ions, The Valencies of Positive and Negative Ions of Concentration Cell with Transference formula is defined as the relation with the total number of ions and with the transport number of anions. Valencies of Positive and Negative Ions is denoted by symbol.

How to calculate Valencies of Positive and Negative Ions of Concentration Cell with Transference using this online calculator? To use this online calculator for Valencies of Positive and Negative Ions of Concentration Cell with Transference, enter Transport Number of Anion (t-), Total number of Ions (ν), Temperature (T), EMF of Cell (EMF), Number of Positive and Negative Ions (v±), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1) and hit the calculate button. Here is how the Valencies of Positive and Negative Ions of Concentration Cell with Transference calculation can be explained with given input values -> 2.805431 = ((49*110*[R]*298)/(0.5*81.35*[Faraday]))*ln(0.36/0.2).

FAQ

What is Valencies of Positive and Negative Ions of Concentration Cell with Transference?
The Valencies of Positive and Negative Ions of Concentration Cell with Transference formula is defined as the relation with the total number of ions and with the transport number of anions and is represented as Z± = ((t-*ν*[R]*T)/(EMF*v±*[Faraday]))*ln(a2/a1) or Valencies of Positive and Negative Ions = ((Transport Number of Anion*Total number of Ions*[R]*Temperature)/(EMF of Cell*Number of Positive and Negative Ions*[Faraday]))*ln(Cathodic Ionic Activity/Anodic Ionic Activity). The Transport Number of Anion is ratio of current carried by anion to total current, The Total number of ions is the number of ions present in the electrolytic solution, Temperature is the degree or intensity of heat present in a substance or object, The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell, The Number of Positive and Negative Ions is the amount of cations and anions present in the electrolytic solution, Cathodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in a cathodic half-cell & The Anodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in an anodic half cell.
How to calculate Valencies of Positive and Negative Ions of Concentration Cell with Transference?
The Valencies of Positive and Negative Ions of Concentration Cell with Transference formula is defined as the relation with the total number of ions and with the transport number of anions is calculated using Valencies of Positive and Negative Ions = ((Transport Number of Anion*Total number of Ions*[R]*Temperature)/(EMF of Cell*Number of Positive and Negative Ions*[Faraday]))*ln(Cathodic Ionic Activity/Anodic Ionic Activity). To calculate Valencies of Positive and Negative Ions of Concentration Cell with Transference, you need Transport Number of Anion (t-), Total number of Ions (ν), Temperature (T), EMF of Cell (EMF), Number of Positive and Negative Ions (v±), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1). With our tool, you need to enter the respective value for Transport Number of Anion, Total number of Ions, Temperature, EMF of Cell, Number of Positive and Negative Ions, Cathodic Ionic Activity & Anodic Ionic Activity and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
Let Others Know
Facebook
Twitter
Reddit
LinkedIn
Email
WhatsApp
Copied!