Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity Solution

STEP 0: Pre-Calculation Summary
Formula Used
Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity/Pressure)))
T = modulus((G-Gig)/([R]*ln(f/P)))
This formula uses 1 Constants, 2 Functions, 5 Variables
Constants Used
[R] - Universal gas constant Value Taken As 8.31446261815324
Functions Used
ln - The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function., ln(Number)
modulus - Modulus of a number is the remainder when that number is divided by another number., modulus
Variables Used
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
Gibbs Free Energy - (Measured in Joule) - Gibbs Free Energy is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure.
Ideal Gas Gibbs Free Energy - (Measured in Joule) - Ideal Gas Gibbs Free Energy is the Gibbs energy in an ideal condition.
Fugacity - (Measured in Pascal) - Fugacity is a thermodynamic property of a real gas which if substituted for the pressure or partial pressure in the equations for an ideal gas gives equations applicable to the real gas.
Pressure - (Measured in Pascal) - Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed.
STEP 1: Convert Input(s) to Base Unit
Gibbs Free Energy: 228.61 Joule --> 228.61 Joule No Conversion Required
Ideal Gas Gibbs Free Energy: 95 Joule --> 95 Joule No Conversion Required
Fugacity: 15 Pascal --> 15 Pascal No Conversion Required
Pressure: 38.4 Pascal --> 38.4 Pascal No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
T = modulus((G-Gig)/([R]*ln(f/P))) --> modulus((228.61-95)/([R]*ln(15/38.4)))
Evaluating ... ...
T = 17.0951758213518
STEP 3: Convert Result to Output's Unit
17.0951758213518 Kelvin --> No Conversion Required
FINAL ANSWER
17.0951758213518 17.09518 Kelvin <-- Temperature
(Calculation completed in 00.004 seconds)

Credits

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Created by Shivam Sinha
National Institute Of Technology (NIT), Surathkal
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Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
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Fugacity and Fugacity Coefficient Calculators

Gibbs Free Energy using Ideal Gibbs Free Energy and Fugacity Coefficient
​ LaTeX ​ Go Gibbs Free Energy = Ideal Gas Gibbs Free Energy+[R]*Temperature*ln(Fugacity Coefficient)
Temperature using Residual Gibbs Free Energy and Fugacity Coefficient
​ LaTeX ​ Go Temperature = modulus(Residual Gibbs Free Energy/([R]*ln(Fugacity Coefficient)))
Fugacity Coefficient using Residual Gibbs Free Energy
​ LaTeX ​ Go Fugacity Coefficient = exp(Residual Gibbs Free Energy/([R]*Temperature))
Residual Gibbs Free Energy using Fugacity Coefficient
​ LaTeX ​ Go Residual Gibbs Free Energy = [R]*Temperature*ln(Fugacity Coefficient)

Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity Formula

​LaTeX ​Go
Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity/Pressure)))
T = modulus((G-Gig)/([R]*ln(f/P)))

What is Gibbs Free Energy?

The Gibbs free energy (or Gibbs energy) is a thermodynamic potential that can be used to calculate the maximum reversible work that may be performed by a thermodynamic system at a constant temperature and pressure. The Gibbs free energy measured in joules in SI) is the maximum amount of non-expansion work that can be extracted from a thermodynamically closed system (can exchange heat and work with its surroundings, but not matter). This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces.

What is Duhem’s Theorem?

For any closed system formed from known amounts of prescribed chemical species, the equilibrium state is completely determined when any two independent variables are fixed. The two independent variables subject to specification may in general be either intensive or extensive. However, the number of independent intensive variables is given by the phase rule. Thus when F = 1, at least one of the two variables must be extensive, and when F = 0, both must be extensive.

How to Calculate Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity?

Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity calculator uses Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity/Pressure))) to calculate the Temperature, The Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity is defined as the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of the universal gas constant and the natural logarithm of the ratio of the fugacity to the pressure. Temperature is denoted by T symbol.

How to calculate Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity using this online calculator? To use this online calculator for Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity, enter Gibbs Free Energy (G), Ideal Gas Gibbs Free Energy (Gig), Fugacity (f) & Pressure (P) and hit the calculate button. Here is how the Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity calculation can be explained with given input values -> 17.09518 = modulus((228.61-95)/([R]*ln(15/38.4))).

FAQ

What is Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity?
The Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity is defined as the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of the universal gas constant and the natural logarithm of the ratio of the fugacity to the pressure and is represented as T = modulus((G-Gig)/([R]*ln(f/P))) or Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity/Pressure))). Gibbs Free Energy is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure, Ideal Gas Gibbs Free Energy is the Gibbs energy in an ideal condition, Fugacity is a thermodynamic property of a real gas which if substituted for the pressure or partial pressure in the equations for an ideal gas gives equations applicable to the real gas & Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed.
How to calculate Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity?
The Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity is defined as the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of the universal gas constant and the natural logarithm of the ratio of the fugacity to the pressure is calculated using Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity/Pressure))). To calculate Temperature using Gibbs Free Energy, Ideal Gibbs Free Energy, Pressure and Fugacity, you need Gibbs Free Energy (G), Ideal Gas Gibbs Free Energy (Gig), Fugacity (f) & Pressure (P). With our tool, you need to enter the respective value for Gibbs Free Energy, Ideal Gas Gibbs Free Energy, Fugacity & Pressure and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Temperature?
In this formula, Temperature uses Gibbs Free Energy, Ideal Gas Gibbs Free Energy, Fugacity & Pressure. We can use 3 other way(s) to calculate the same, which is/are as follows -
  • Temperature = modulus(Residual Gibbs Free Energy/([R]*ln(Fugacity Coefficient)))
  • Temperature = Residual Gibbs Free Energy/([R]*ln(Fugacity/Pressure))
  • Temperature = modulus((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*ln(Fugacity Coefficient)))
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