Temperature of Concentration Cell without Transference given Molalities Calculator

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✖The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.ⓘ EMF of Cell [E_cell]			+10% -10%
✖The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.ⓘ Cathodic Electrolyte Molality [m₂]			+10% -10%
✖The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell.ⓘ Cathodic Activity Coefficient [γ₂]			+10% -10%
✖The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell.ⓘ Anodic Electrolyte Molality [m₁]			+10% -10%
✖The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.ⓘ Anodic Activity Coefficient [γ₁]			+10% -10%

✖The temperature of liquid is the degree or intensity of heat present in a liquid.ⓘ Temperature of Concentration Cell without Transference given Molalities [T]

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Temperature of Concentration Cell without Transference given Molalities Solution

STEP 0: Pre-Calculation Summary

Formula Used

Temperature of Liquid = (EMF of Cell*([Faraday]/2*[R]))/(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient)))
T = (E_cell*([Faraday]/2*[R]))/(ln((m₂*γ₂)/(m₁*γ₁)))
This formula uses 2 Constants, 1 Functions, 6 Variables

Constants Used

[Faraday] - Faraday constant Value Taken As 96485.33212
[R] - Universal gas constant Value Taken As 8.31446261815324

Functions Used

ln - The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function., ln(Number)

Variables Used

Temperature of Liquid - (Measured in Kelvin) - The temperature of liquid is the degree or intensity of heat present in a liquid.
EMF of Cell - (Measured in Volt) - The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Cathodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.
Cathodic Activity Coefficient - The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell.
Anodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell.
Anodic Activity Coefficient - The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.

STEP 1: Convert Input(s) to Base Unit

EMF of Cell: 0.51 Volt --> 0.51 Volt No Conversion Required
Cathodic Electrolyte Molality: 0.13 Mole per Kilogram --> 0.13 Mole per Kilogram No Conversion Required
Cathodic Activity Coefficient: 0.1 --> No Conversion Required
Anodic Electrolyte Molality: 0.4 Mole per Kilogram --> 0.4 Mole per Kilogram No Conversion Required
Anodic Activity Coefficient: 5.5 --> No Conversion Required

STEP 2: Evaluate Formula

Substituting Input Values in Formula

T = (E_cell*([Faraday]/2*[R]))/(ln((m₂*γ₂)/(m₁*γ₁))) --> (0.51*([Faraday]/2*[R]))/(ln((0.13*0.1)/(0.4*5.5)))

Evaluating ... ...

T = -39866.7986762074

STEP 3: Convert Result to Output's Unit

-39866.7986762074 Kelvin --> No Conversion Required

FINAL ANSWER

-39866.7986762074 ≈ -39866.798676 Kelvin <-- Temperature of Liquid

(Calculation completed in 00.021 seconds)

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Created by Prashant Singh

K J Somaiya College of science (K J Somaiya), Mumbai

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University of Hawaiʻi at Mānoa (UH Manoa), Hawaii, USA

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Temperature of Concentration Cell without Transference given Molalities Formula

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What is Concentration cell without transference?

A cell in which the transference of a substance from a system of high concentration to one at low concentration results in the production of electrical energy is called a concentration cell. It consists of two half cells having two identical electrodes and identical electrolytes but with different concentrations. EMF of this cell depends upon the difference of concentration. Concentration cell without transference is no direct transference of electrolyte but it occurs due to the result of the chemical reaction. Each electrode is reversible with respect to one of the ions of the electrolyte.

How to Calculate Temperature of Concentration Cell without Transference given Molalities?

Temperature of Concentration Cell without Transference given Molalities calculator uses Temperature of Liquid = (EMF of Cell*([Faraday]/2*[R]))/(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))) to calculate the Temperature of Liquid, The Temperature of concentration cell without transference given molalities formula is defined as the relation of emf of the cell and molaity and activity coefficient of electrolyte at cathode and anode half cell. Temperature of Liquid is denoted by T symbol.

How to calculate Temperature of Concentration Cell without Transference given Molalities using this online calculator? To use this online calculator for Temperature of Concentration Cell without Transference given Molalities, enter EMF of Cell (E_cell), Cathodic Electrolyte Molality (m₂), Cathodic Activity Coefficient (γ₂), Anodic Electrolyte Molality (m₁) & Anodic Activity Coefficient (γ₁) and hit the calculate button. Here is how the Temperature of Concentration Cell without Transference given Molalities calculation can be explained with given input values -> -39866.798676 = (0.51*([Faraday]/2*[R]))/(ln((0.13*0.1)/(0.4*5.5))).

FAQ

What is Temperature of Concentration Cell without Transference given Molalities?

The Temperature of concentration cell without transference given molalities formula is defined as the relation of emf of the cell and molaity and activity coefficient of electrolyte at cathode and anode half cell and is represented as T = (E_cell*([Faraday]/2*[R]))/(ln((m₂*γ₂)/(m₁*γ₁))) or Temperature of Liquid = (EMF of Cell*([Faraday]/2*[R]))/(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))). The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell, The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell, The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell, The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell & The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.

How to calculate Temperature of Concentration Cell without Transference given Molalities?

The Temperature of concentration cell without transference given molalities formula is defined as the relation of emf of the cell and molaity and activity coefficient of electrolyte at cathode and anode half cell is calculated using Temperature of Liquid = (EMF of Cell*([Faraday]/2*[R]))/(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))). To calculate Temperature of Concentration Cell without Transference given Molalities, you need EMF of Cell (E_cell), Cathodic Electrolyte Molality (m₂), Cathodic Activity Coefficient (γ₂), Anodic Electrolyte Molality (m₁) & Anodic Activity Coefficient (γ₁). With our tool, you need to enter the respective value for EMF of Cell, Cathodic Electrolyte Molality, Cathodic Activity Coefficient, Anodic Electrolyte Molality & Anodic Activity Coefficient and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.

How many ways are there to calculate Temperature of Liquid?

In this formula, Temperature of Liquid uses EMF of Cell, Cathodic Electrolyte Molality, Cathodic Activity Coefficient, Anodic Electrolyte Molality & Anodic Activity Coefficient. We can use 3 other way(s) to calculate the same, which is/are as follows -

Temperature of Liquid = Internal Energy/(Entropy-Helmholtz Free Entropy)
Temperature of Liquid = -(Helmholtz Free Energy of System/Helmholtz Free Entropy)
Temperature of Liquid = ((Internal Energy+(Pressure*Volume))/(Entropy-Gibbs Free Entropy))

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