Temperature of concentration cell with transference given valencies Solution

STEP 0: Pre-Calculation Summary
Formula Used
Temperature of Liquid = ((EMF of Cell*Number of Positive and Negative Ions*Valencies of Positive and Negative Ions*[Faraday])/(Transport Number of Anion*Total number of Ions*[R]))/ln(Cathodic Ionic Activity/Anodic Ionic Activity)
T = ((Ecell*ν±**[Faraday])/(t-*ν*[R]))/ln(a2/a1)
This formula uses 2 Constants, 1 Functions, 8 Variables
Constants Used
[Faraday] - Faraday constant Value Taken As 96485.33212
[R] - Universal gas constant Value Taken As 8.31446261815324
Functions Used
ln - The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function., ln(Number)
Variables Used
Temperature of Liquid - (Measured in Kelvin) - The temperature of liquid is the degree or intensity of heat present in a liquid.
EMF of Cell - (Measured in Volt) - The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Number of Positive and Negative Ions - The Number of Positive and Negative Ions is the amount of cations and anions present in the electrolytic solution.
Valencies of Positive and Negative Ions - The Valencies of positive and negative ions is the valency of electrolytes with respect to electrodes with which ions are reversible.
Transport Number of Anion - The Transport Number of Anion is ratio of current carried by anion to total current.
Total number of Ions - The Total number of ions is the number of ions present in the electrolytic solution.
Cathodic Ionic Activity - (Measured in Mole per Kilogram) - Cathodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in a cathodic half-cell.
Anodic Ionic Activity - (Measured in Mole per Kilogram) - The Anodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in an anodic half cell.
STEP 1: Convert Input(s) to Base Unit
EMF of Cell: 0.51 Volt --> 0.51 Volt No Conversion Required
Number of Positive and Negative Ions: 58 --> No Conversion Required
Valencies of Positive and Negative Ions: 2 --> No Conversion Required
Transport Number of Anion: 49 --> No Conversion Required
Total number of Ions: 110 --> No Conversion Required
Cathodic Ionic Activity: 0.36 Mole per Kilogram --> 0.36 Mole per Kilogram No Conversion Required
Anodic Ionic Activity: 0.2 Mole per Kilogram --> 0.2 Mole per Kilogram No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
T = ((Ecell*ν±*Z±*[Faraday])/(t-*ν*[R]))/ln(a2/a1) --> ((0.51*58*2*[Faraday])/(49*110*[R]))/ln(0.36/0.2)
Evaluating ... ...
T = 216.693947993883
STEP 3: Convert Result to Output's Unit
216.693947993883 Kelvin --> No Conversion Required
FINAL ANSWER
216.693947993883 216.6939 Kelvin <-- Temperature of Liquid
(Calculation completed in 00.004 seconds)

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K J Somaiya College of science (K J Somaiya), Mumbai
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Temperature of concentration cell with transference given valencies Formula

​LaTeX ​Go
Temperature of Liquid = ((EMF of Cell*Number of Positive and Negative Ions*Valencies of Positive and Negative Ions*[Faraday])/(Transport Number of Anion*Total number of Ions*[R]))/ln(Cathodic Ionic Activity/Anodic Ionic Activity)
T = ((Ecell*ν±**[Faraday])/(t-*ν*[R]))/ln(a2/a1)

What is concentration cell with transference?

A cell in which the transference of a substance from a system of high concentration to one at low concentration results in the production of electrical energy is called a concentration cell. It consists of two half cells having two identical electrodes and identical electrolytes but with different concentrations. EMF of this cell depends upon the difference of concentration. In a concentration cell with transference, there is a direct transference of electrolytes. The same electrode is reversible with respect to one of the ions of the electrolyte.

How to Calculate Temperature of concentration cell with transference given valencies?

Temperature of concentration cell with transference given valencies calculator uses Temperature of Liquid = ((EMF of Cell*Number of Positive and Negative Ions*Valencies of Positive and Negative Ions*[Faraday])/(Transport Number of Anion*Total number of Ions*[R]))/ln(Cathodic Ionic Activity/Anodic Ionic Activity) to calculate the Temperature of Liquid, The Temperature of concentration cell with transference given valencies formula is defined as the relation with the total number of ions and the valencies of the electrolytes. Temperature of Liquid is denoted by T symbol.

How to calculate Temperature of concentration cell with transference given valencies using this online calculator? To use this online calculator for Temperature of concentration cell with transference given valencies, enter EMF of Cell (Ecell), Number of Positive and Negative Ions (ν±), Valencies of Positive and Negative Ions (Z±), Transport Number of Anion (t-), Total number of Ions (ν), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1) and hit the calculate button. Here is how the Temperature of concentration cell with transference given valencies calculation can be explained with given input values -> 216.6939 = ((0.51*58*2*[Faraday])/(49*110*[R]))/ln(0.36/0.2).

FAQ

What is Temperature of concentration cell with transference given valencies?
The Temperature of concentration cell with transference given valencies formula is defined as the relation with the total number of ions and the valencies of the electrolytes and is represented as T = ((Ecell*ν±*Z±*[Faraday])/(t-*ν*[R]))/ln(a2/a1) or Temperature of Liquid = ((EMF of Cell*Number of Positive and Negative Ions*Valencies of Positive and Negative Ions*[Faraday])/(Transport Number of Anion*Total number of Ions*[R]))/ln(Cathodic Ionic Activity/Anodic Ionic Activity). The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell, The Number of Positive and Negative Ions is the amount of cations and anions present in the electrolytic solution, The Valencies of positive and negative ions is the valency of electrolytes with respect to electrodes with which ions are reversible, The Transport Number of Anion is ratio of current carried by anion to total current, The Total number of ions is the number of ions present in the electrolytic solution, Cathodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in a cathodic half-cell & The Anodic Ionic Activity is the measure of the effective concentration of a molecule or ionic species in an anodic half cell.
How to calculate Temperature of concentration cell with transference given valencies?
The Temperature of concentration cell with transference given valencies formula is defined as the relation with the total number of ions and the valencies of the electrolytes is calculated using Temperature of Liquid = ((EMF of Cell*Number of Positive and Negative Ions*Valencies of Positive and Negative Ions*[Faraday])/(Transport Number of Anion*Total number of Ions*[R]))/ln(Cathodic Ionic Activity/Anodic Ionic Activity). To calculate Temperature of concentration cell with transference given valencies, you need EMF of Cell (Ecell), Number of Positive and Negative Ions (ν±), Valencies of Positive and Negative Ions (Z±), Transport Number of Anion (t-), Total number of Ions (ν), Cathodic Ionic Activity (a2) & Anodic Ionic Activity (a1). With our tool, you need to enter the respective value for EMF of Cell, Number of Positive and Negative Ions, Valencies of Positive and Negative Ions, Transport Number of Anion, Total number of Ions, Cathodic Ionic Activity & Anodic Ionic Activity and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Temperature of Liquid?
In this formula, Temperature of Liquid uses EMF of Cell, Number of Positive and Negative Ions, Valencies of Positive and Negative Ions, Transport Number of Anion, Total number of Ions, Cathodic Ionic Activity & Anodic Ionic Activity. We can use 3 other way(s) to calculate the same, which is/are as follows -
  • Temperature of Liquid = Internal Energy/(Entropy-Helmholtz Free Entropy)
  • Temperature of Liquid = -(Helmholtz Free Energy of System/Helmholtz Free Entropy)
  • Temperature of Liquid = ((Internal Energy+(Pressure*Volume))/(Entropy-Gibbs Free Entropy))
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