Rate Constant for Backward Reaction Solution

STEP 0: Pre-Calculation Summary
Formula Used
Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2
kbrc' = kf*(A0-xeq)/xeq^2
This formula uses 4 Variables
Variables Used
Rate Constant of Backward Reaction - (Measured in Cubic Meter per Mole Second) - Rate Constant of Backward Reaction for 2nd Order is the proportionality constant relating the rate of the chemical reaction to the conc. of reactant or product in a backward reaction.
Forward Reaction Rate Constant - (Measured in 1 Per Second) - Forward Reaction Rate Constant is used to define the relationship between the molar concentration of the reactants and the rate of the chemical reaction in forward direction.
Initial Concentration of Reactant A - (Measured in Mole per Cubic Meter) - Initial Concentration of Reactant A is defined as the concentration of the reactant A at time t=0.
Concentration of Reactant at Equilibrium - (Measured in Mole per Cubic Meter) - Concentration of Reactant at Equilibrium is defined as the amount of reactant present when the reaction is at equilibrium condition.
STEP 1: Convert Input(s) to Base Unit
Forward Reaction Rate Constant: 9.74E-05 1 Per Second --> 9.74E-05 1 Per Second No Conversion Required
Initial Concentration of Reactant A: 100 Mole per Liter --> 100000 Mole per Cubic Meter (Check conversion ​here)
Concentration of Reactant at Equilibrium: 70 Mole per Liter --> 70000 Mole per Cubic Meter (Check conversion ​here)
STEP 2: Evaluate Formula
Substituting Input Values in Formula
kbrc' = kf*(A0-xeq)/xeq^2 --> 9.74E-05*(100000-70000)/70000^2
Evaluating ... ...
kbrc' = 5.96326530612245E-10
STEP 3: Convert Result to Output's Unit
5.96326530612245E-10 Cubic Meter per Mole Second -->5.96326530612245E-07 Liter per Mole Second (Check conversion ​here)
FINAL ANSWER
5.96326530612245E-07 6E-7 Liter per Mole Second <-- Rate Constant of Backward Reaction
(Calculation completed in 00.004 seconds)

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First Order Opposed by Second Order Reactions Calculators

Time Taken for Completion of Reaction
​ LaTeX ​ Go Time = (1/Forward Reaction Rate Constant)*(Concentration of Reactant at Equilibrium/(2*Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium))*ln((Initial Concentration of Reactant A*Concentration of Reactant at Equilibrium+Concentration of Product at Time t*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium))/(Initial Concentration of Reactant A*(Concentration of Reactant at Equilibrium-Concentration of Product at Time t)))
Rate Constant for Forward Reaction
​ LaTeX ​ Go Forward Reaction Rate Constant = (1/Time)*(Concentration of Reactant at Equilibrium/(2*Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium))*ln((Initial Concentration of Reactant A*Concentration of Reactant at Equilibrium+Concentration of Product at Time t*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium))/(Initial Concentration of Reactant A*(Concentration of Reactant at Equilibrium-Concentration of Product at Time t)))
Rate Constant for Backward Reaction
​ LaTeX ​ Go Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2

Important Formulas on Reversible Reaction Calculators

Reactant Concentration at given Time t
​ LaTeX ​ Go Concentration of A at Time t = Initial Concentration of Reactant A*(Forward Reaction Rate Constant/(Forward Reaction Rate Constant+Backward Reaction Rate Constant))*((Backward Reaction Rate Constant/Forward Reaction Rate Constant)+exp(-(Forward Reaction Rate Constant+Backward Reaction Rate Constant)*Time))
Product Conc for 1st Order Opposed by 1st Order Rxn given Initial Conc of B greater than 0
​ LaTeX ​ Go Concentration of Product at Time t = Concentration of Reactant at Equilibrium*(1-exp(-Forward Reaction Rate Constant*((Initial Concentration of Reactant A+Initial Concentration of Reactant B)/(Initial Concentration of Reactant B+Concentration of Reactant at Equilibrium))*Time))
Product Conc of First Order Opposed by First Order Reaction given Initial Conc of Reactant
​ LaTeX ​ Go Concentration of Product at Time t = Concentration of Reactant at Equilibrium*(1-exp(-Forward Reaction Rate Constant*Time*(Initial Concentration of Reactant A/Concentration of Reactant at Equilibrium)))
Product Concentration of 1st Order Opposed by 1st Order Reaction at given Time t
​ LaTeX ​ Go Concentration of Product at Time t = Concentration of Reactant at Equilibrium*(1-exp(-(Forward Reaction Rate Constant+Backward Reaction Rate Constant)*Time))

Rate Constant for Backward Reaction Formula

​LaTeX ​Go
Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2
kbrc' = kf*(A0-xeq)/xeq^2

What is an Opposing Reaction?

Opposing reactions or reversible reactions are those in which both forward and backward reaction takes place simultaneously. To start with, the rate of forward reaction is very large and it decreases as reactant concentration decreases with time. Similarly, initially the rate of backward reaction is slow and it increases as product concentration increases with time. The state at which the rate of forward reaction equals the rate of backward reaction is called the equilibrium state. Thus, equilibrium is a dynamic equilibrium where all the participants of a reaction are being formed as fast as they are being destroyed and hence no further change in the various concentrations is observed.

What are the classifications of Opposing Reactions?

A reversible reaction may be classified on the basis of orders of elementary forward and backward reactions. We describe below a few reversible reactions classified accordingly:
1. First Order Opposed by First Order Reaction
2. First Order Opposed by Second Order Reaction
3. Second Order Opposed by First Order Reaction
4. Second Order Opposed by Second Order Reaction.

How to Calculate Rate Constant for Backward Reaction?

Rate Constant for Backward Reaction calculator uses Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2 to calculate the Rate Constant of Backward Reaction, The Rate Constant for Backward Reaction formula is defined as the proportionality constant relating the rate of the chemical reaction at a given temperature to the concentration of the reactant or product in a backward reaction. Rate Constant of Backward Reaction is denoted by kbrc' symbol.

How to calculate Rate Constant for Backward Reaction using this online calculator? To use this online calculator for Rate Constant for Backward Reaction, enter Forward Reaction Rate Constant (kf), Initial Concentration of Reactant A (A0) & Concentration of Reactant at Equilibrium (xeq) and hit the calculate button. Here is how the Rate Constant for Backward Reaction calculation can be explained with given input values -> 6E-10 = 9.74E-05*(100000-70000)/70000^2.

FAQ

What is Rate Constant for Backward Reaction?
The Rate Constant for Backward Reaction formula is defined as the proportionality constant relating the rate of the chemical reaction at a given temperature to the concentration of the reactant or product in a backward reaction and is represented as kbrc' = kf*(A0-xeq)/xeq^2 or Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2. Forward Reaction Rate Constant is used to define the relationship between the molar concentration of the reactants and the rate of the chemical reaction in forward direction, Initial Concentration of Reactant A is defined as the concentration of the reactant A at time t=0 & Concentration of Reactant at Equilibrium is defined as the amount of reactant present when the reaction is at equilibrium condition.
How to calculate Rate Constant for Backward Reaction?
The Rate Constant for Backward Reaction formula is defined as the proportionality constant relating the rate of the chemical reaction at a given temperature to the concentration of the reactant or product in a backward reaction is calculated using Rate Constant of Backward Reaction = Forward Reaction Rate Constant*(Initial Concentration of Reactant A-Concentration of Reactant at Equilibrium)/Concentration of Reactant at Equilibrium^2. To calculate Rate Constant for Backward Reaction, you need Forward Reaction Rate Constant (kf), Initial Concentration of Reactant A (A0) & Concentration of Reactant at Equilibrium (xeq). With our tool, you need to enter the respective value for Forward Reaction Rate Constant, Initial Concentration of Reactant A & Concentration of Reactant at Equilibrium and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
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