Madelung Constant using Madelung Energy Solution

STEP 0: Pre-Calculation Summary
Formula Used
Madelung Constant = (-(Madelung Energy)*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((Charge^2)*([Charge-e]^2))
M = (-(EM)*4*pi*[Permitivity-vacuum]*r0)/((q^2)*([Charge-e]^2))
This formula uses 3 Constants, 4 Variables
Constants Used
[Permitivity-vacuum] - Permittivity of vacuum Value Taken As 8.85E-12
[Charge-e] - Charge of electron Value Taken As 1.60217662E-19
pi - Archimedes' constant Value Taken As 3.14159265358979323846264338327950288
Variables Used
Madelung Constant - The Madelung constant is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges.
Madelung Energy - (Measured in Joule) - The Madelung Energy for a simple lattice consisting ions with equal and opposite charge in a 1:1 ratio is the sum of interactions between one ion and all other lattice ions.
Distance of Closest Approach - (Measured in Meter) - Distance of Closest Approach is the distance to which an alpha particle comes closer to the nucleus.
Charge - (Measured in Coulomb) - A Charge is the fundamental property of forms of matter that exhibit electrostatic attraction or repulsion in the presence of other matter.
STEP 1: Convert Input(s) to Base Unit
Madelung Energy: -5.9E-21 Joule --> -5.9E-21 Joule No Conversion Required
Distance of Closest Approach: 60 Angstrom --> 6E-09 Meter (Check conversion ​here)
Charge: 0.3 Coulomb --> 0.3 Coulomb No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
M = (-(EM)*4*pi*[Permitivity-vacuum]*r0)/((q^2)*([Charge-e]^2)) --> (-((-5.9E-21))*4*pi*[Permitivity-vacuum]*6E-09)/((0.3^2)*([Charge-e]^2))
Evaluating ... ...
M = 1.70409227389962
STEP 3: Convert Result to Output's Unit
1.70409227389962 --> No Conversion Required
FINAL ANSWER
1.70409227389962 1.704092 <-- Madelung Constant
(Calculation completed in 00.004 seconds)

Credits

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Created by Prerana Bakli
University of Hawaiʻi at Mānoa (UH Manoa), Hawaii, USA
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Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
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Madelung Constant Calculators

Madelung Constant using Born-Mayer equation
​ LaTeX ​ Go Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach)))
Madelung Constant using Born Lande Equation
​ LaTeX ​ Go Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((1-(1/Born Exponent))*([Charge-e]^2)*[Avaga-no]*Charge of Cation*Charge of Anion)
Madelung Constant given Repulsive Interaction Constant
​ LaTeX ​ Go Madelung Constant = (Repulsive Interaction Constant given M*4*pi*[Permitivity-vacuum]*Born Exponent)/((Charge^2)*([Charge-e]^2)*(Distance of Closest Approach^(Born Exponent-1)))
Madelung Constant using Kapustinskii Approximation
​ LaTeX ​ Go Madelung Constant = 0.88*Number of Ions

Madelung Constant using Madelung Energy Formula

​LaTeX ​Go
Madelung Constant = (-(Madelung Energy)*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((Charge^2)*([Charge-e]^2))
M = (-(EM)*4*pi*[Permitivity-vacuum]*r0)/((q^2)*([Charge-e]^2))

What is Born–Landé equation?

The Born–Landé equation is a means of calculating the lattice energy of a crystalline ionic compound. In 1918 Max Born and Alfred Landé proposed that the lattice energy could be derived from the electrostatic potential of the ionic lattice and a repulsive potential energy term. The ionic lattice is modeled as an assembly of hard elastic spheres which are compressed together by the mutual attraction of the electrostatic charges on the ions. They achieve the observed equilibrium distance apart due to a balancing short range repulsion.

How to Calculate Madelung Constant using Madelung Energy?

Madelung Constant using Madelung Energy calculator uses Madelung Constant = (-(Madelung Energy)*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((Charge^2)*([Charge-e]^2)) to calculate the Madelung Constant, The Madelung constant using Madelung Energy is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges. Madelung Constant is denoted by M symbol.

How to calculate Madelung Constant using Madelung Energy using this online calculator? To use this online calculator for Madelung Constant using Madelung Energy, enter Madelung Energy (EM), Distance of Closest Approach (r0) & Charge (q) and hit the calculate button. Here is how the Madelung Constant using Madelung Energy calculation can be explained with given input values -> 1.704092 = (-((-5.9E-21))*4*pi*[Permitivity-vacuum]*6E-09)/((0.3^2)*([Charge-e]^2)).

FAQ

What is Madelung Constant using Madelung Energy?
The Madelung constant using Madelung Energy is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges and is represented as M = (-(EM)*4*pi*[Permitivity-vacuum]*r0)/((q^2)*([Charge-e]^2)) or Madelung Constant = (-(Madelung Energy)*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((Charge^2)*([Charge-e]^2)). The Madelung Energy for a simple lattice consisting ions with equal and opposite charge in a 1:1 ratio is the sum of interactions between one ion and all other lattice ions, Distance of Closest Approach is the distance to which an alpha particle comes closer to the nucleus & A Charge is the fundamental property of forms of matter that exhibit electrostatic attraction or repulsion in the presence of other matter.
How to calculate Madelung Constant using Madelung Energy?
The Madelung constant using Madelung Energy is used in determining the electrostatic potential of a single ion in a crystal by approximating the ions by point charges is calculated using Madelung Constant = (-(Madelung Energy)*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((Charge^2)*([Charge-e]^2)). To calculate Madelung Constant using Madelung Energy, you need Madelung Energy (EM), Distance of Closest Approach (r0) & Charge (q). With our tool, you need to enter the respective value for Madelung Energy, Distance of Closest Approach & Charge and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Madelung Constant?
In this formula, Madelung Constant uses Madelung Energy, Distance of Closest Approach & Charge. We can use 3 other way(s) to calculate the same, which is/are as follows -
  • Madelung Constant = (Repulsive Interaction Constant given M*4*pi*[Permitivity-vacuum]*Born Exponent)/((Charge^2)*([Charge-e]^2)*(Distance of Closest Approach^(Born Exponent-1)))
  • Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/((1-(1/Born Exponent))*([Charge-e]^2)*[Avaga-no]*Charge of Cation*Charge of Anion)
  • Madelung Constant = (-Lattice Energy*4*pi*[Permitivity-vacuum]*Distance of Closest Approach)/([Avaga-no]*Charge of Cation*Charge of Anion*([Charge-e]^2)*(1-(Constant Depending on Compressibility/Distance of Closest Approach)))
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