Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure Solution

STEP 0: Pre-Calculation Summary
Formula Used
Fugacity = Pressure*exp((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*Temperature))
f = P*exp((G-Gig)/([R]*T))
This formula uses 1 Constants, 1 Functions, 5 Variables
Constants Used
[R] - Universal gas constant Value Taken As 8.31446261815324
Functions Used
exp - n an exponential function, the value of the function changes by a constant factor for every unit change in the independent variable., exp(Number)
Variables Used
Fugacity - (Measured in Pascal) - Fugacity is a thermodynamic property of a real gas which if substituted for the pressure or partial pressure in the equations for an ideal gas gives equations applicable to the real gas.
Pressure - (Measured in Pascal) - Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed.
Gibbs Free Energy - (Measured in Joule) - Gibbs Free Energy is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure.
Ideal Gas Gibbs Free Energy - (Measured in Joule) - Ideal Gas Gibbs Free Energy is the Gibbs energy in an ideal condition.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
STEP 1: Convert Input(s) to Base Unit
Pressure: 38.4 Pascal --> 38.4 Pascal No Conversion Required
Gibbs Free Energy: 228.61 Joule --> 228.61 Joule No Conversion Required
Ideal Gas Gibbs Free Energy: 95 Joule --> 95 Joule No Conversion Required
Temperature: 450 Kelvin --> 450 Kelvin No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
f = P*exp((G-Gig)/([R]*T)) --> 38.4*exp((228.61-95)/([R]*450))
Evaluating ... ...
f = 39.79604988186
STEP 3: Convert Result to Output's Unit
39.79604988186 Pascal --> No Conversion Required
FINAL ANSWER
39.79604988186 39.79605 Pascal <-- Fugacity
(Calculation completed in 00.021 seconds)

Credits

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Created by Shivam Sinha
National Institute Of Technology (NIT), Surathkal
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Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
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Fugacity and Fugacity Coefficient Calculators

Gibbs Free Energy using Ideal Gibbs Free Energy and Fugacity Coefficient
​ LaTeX ​ Go Gibbs Free Energy = Ideal Gas Gibbs Free Energy+[R]*Temperature*ln(Fugacity Coefficient)
Temperature using Residual Gibbs Free Energy and Fugacity Coefficient
​ LaTeX ​ Go Temperature = modulus(Residual Gibbs Free Energy/([R]*ln(Fugacity Coefficient)))
Fugacity Coefficient using Residual Gibbs Free Energy
​ LaTeX ​ Go Fugacity Coefficient = exp(Residual Gibbs Free Energy/([R]*Temperature))
Residual Gibbs Free Energy using Fugacity Coefficient
​ LaTeX ​ Go Residual Gibbs Free Energy = [R]*Temperature*ln(Fugacity Coefficient)

Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure Formula

​LaTeX ​Go
Fugacity = Pressure*exp((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*Temperature))
f = P*exp((G-Gig)/([R]*T))

What is Gibbs Free Energy?

The Gibbs free energy (or Gibbs energy) is a thermodynamic potential that can be used to calculate the maximum reversible work that may be performed by a thermodynamic system at a constant temperature and pressure. The Gibbs free energy measured in joules in SI) is the maximum amount of non-expansion work that can be extracted from a thermodynamically closed system (can exchange heat and work with its surroundings, but not matter). This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces.

What is Duhem’s Theorem?

For any closed system formed from known amounts of prescribed chemical species, the equilibrium state is completely determined when any two independent variables are fixed. The two independent variables subject to specification may in general be either intensive or extensive. However, the number of independent intensive variables is given by the phase rule. Thus when F = 1, at least one of the two variables must be extensive, and when F = 0, both must be extensive.

How to Calculate Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure?

Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure calculator uses Fugacity = Pressure*exp((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*Temperature)) to calculate the Fugacity, The Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure formula is defined as the product of the pressure and the exponential of the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of universal gas constant and temperature. Fugacity is denoted by f symbol.

How to calculate Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure using this online calculator? To use this online calculator for Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure, enter Pressure (P), Gibbs Free Energy (G), Ideal Gas Gibbs Free Energy (Gig) & Temperature (T) and hit the calculate button. Here is how the Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure calculation can be explained with given input values -> 39.79605 = 38.4*exp((228.61-95)/([R]*450)).

FAQ

What is Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure?
The Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure formula is defined as the product of the pressure and the exponential of the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of universal gas constant and temperature and is represented as f = P*exp((G-Gig)/([R]*T)) or Fugacity = Pressure*exp((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*Temperature)). Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed, Gibbs Free Energy is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure, Ideal Gas Gibbs Free Energy is the Gibbs energy in an ideal condition & Temperature is the degree or intensity of heat present in a substance or object.
How to calculate Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure?
The Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure formula is defined as the product of the pressure and the exponential of the ratio of the difference of actual Gibbs free energy by the ideal Gibbs free energy to the product of universal gas constant and temperature is calculated using Fugacity = Pressure*exp((Gibbs Free Energy-Ideal Gas Gibbs Free Energy)/([R]*Temperature)). To calculate Fugacity using Gibbs Free Energy, Ideal Gibbs Free Energy and Pressure, you need Pressure (P), Gibbs Free Energy (G), Ideal Gas Gibbs Free Energy (Gig) & Temperature (T). With our tool, you need to enter the respective value for Pressure, Gibbs Free Energy, Ideal Gas Gibbs Free Energy & Temperature and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Fugacity?
In this formula, Fugacity uses Pressure, Gibbs Free Energy, Ideal Gas Gibbs Free Energy & Temperature. We can use 1 other way(s) to calculate the same, which is/are as follows -
  • Fugacity = Pressure*exp(Residual Gibbs Free Energy/([R]*Temperature))
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