Fugacity of Liq. Phase Species using Poynting Factor Correlation Solution

STEP 0: Pre-Calculation Summary
Formula Used
Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature))
fl = ϕsat*Psat*exp((Vl*(P-Psat))/([R]*T))
This formula uses 1 Constants, 1 Functions, 6 Variables
Constants Used
[R] - Universal gas constant Value Taken As 8.31446261815324
Functions Used
exp - n an exponential function, the value of the function changes by a constant factor for every unit change in the independent variable., exp(Number)
Variables Used
Fugacity of Liquid Phase Species - (Measured in Pascal) - Fugacity of Liquid Phase Species is denoted by fl symbol.
Saturated Fugacity Coefficient of Species - Saturated Fugacity Coefficient of Species is the ratio of the saturated fugacity of a species to the saturated pressure of a species.
Saturated Pressure - (Measured in Pascal) - Saturated pressure is the pressure at which a given liquid and its vapour or a given solid and its vapour can co-exist in equilibrium, at a given temperature.
Volume of Liquid Phase - (Measured in Cubic Meter) - Volume of Liquid Phase is the volume of a component in liquid phase.
Pressure - (Measured in Pascal) - Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
STEP 1: Convert Input(s) to Base Unit
Saturated Fugacity Coefficient of Species: 0.13 --> No Conversion Required
Saturated Pressure: 20 Pascal --> 20 Pascal No Conversion Required
Volume of Liquid Phase: 120 Cubic Meter --> 120 Cubic Meter No Conversion Required
Pressure: 38.4 Pascal --> 38.4 Pascal No Conversion Required
Temperature: 450 Kelvin --> 450 Kelvin No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
fl = ϕsat*Psat*exp((Vl*(P-Psat))/([R]*T)) --> 0.13*20*exp((120*(38.4-20))/([R]*450))
Evaluating ... ...
fl = 4.69100948094633
STEP 3: Convert Result to Output's Unit
4.69100948094633 Pascal --> No Conversion Required
FINAL ANSWER
4.69100948094633 4.691009 Pascal <-- Fugacity of Liquid Phase Species
(Calculation completed in 00.190 seconds)

Credits

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Created by Shivam Sinha
National Institute Of Technology (NIT), Surathkal
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Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
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Fugacity and Fugacity Coefficient Calculators

Saturated Fugacity Coeff. using Poynting Factor Correlation and Fugacity of Liq. Phase Species
​ LaTeX ​ Go Saturated Fugacity Coefficient of Species = Fugacity of Liquid Phase Species/(Saturated Pressure*exp((-Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature)))
Fugacity of Liq. Phase Species using Poynting Factor Correlation
​ LaTeX ​ Go Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature))
Poynting Factor
​ LaTeX ​ Go Poynting Factor = exp((-Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature))
Fugacity of Liq. Phase Species using Poynting Factor
​ LaTeX ​ Go Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*Poynting Factor

Fugacity of Liq. Phase Species using Poynting Factor Correlation Formula

​LaTeX ​Go
Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature))
fl = ϕsat*Psat*exp((Vl*(P-Psat))/([R]*T))

What is Poynting Factor?

The Poynting effect generally refers to the change in the fugacity of a liquid when a non-condensable gas is mixed with the vapor at saturated conditions. at high pressure while remaining in the gaseous form is due to the Poynting effect. The Poynting factor can be stated as the change in fugacity as the pressure goes from the saturated pressure to pressure at a constant temperature.

What is Duhem’s Theorem?

For any closed system formed from known amounts of prescribed chemical species, the equilibrium state is completely determined when any two independent variables are fixed. The two independent variables subject to specification may in general be either intensive or extensive. However, the number of independent intensive variables is given by the phase rule. Thus when F = 1, at least one of the two variables must be extensive, and when F = 0, both must be extensive.

How to Calculate Fugacity of Liq. Phase Species using Poynting Factor Correlation?

Fugacity of Liq. Phase Species using Poynting Factor Correlation calculator uses Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature)) to calculate the Fugacity of Liquid Phase Species, The Fugacity of Liq. Phase Species using Poynting Factor Correlation formula is defined as the function of saturated fugacity coefficient of a species, saturated pressure, volume of the liquid phase of a component, pressure, saturated pressure and temperature. Fugacity of Liquid Phase Species is denoted by fl symbol.

How to calculate Fugacity of Liq. Phase Species using Poynting Factor Correlation using this online calculator? To use this online calculator for Fugacity of Liq. Phase Species using Poynting Factor Correlation, enter Saturated Fugacity Coefficient of Species sat), Saturated Pressure (Psat), Volume of Liquid Phase (Vl), Pressure (P) & Temperature (T) and hit the calculate button. Here is how the Fugacity of Liq. Phase Species using Poynting Factor Correlation calculation can be explained with given input values -> 4.691009 = 0.13*20*exp((120*(38.4-20))/([R]*450)).

FAQ

What is Fugacity of Liq. Phase Species using Poynting Factor Correlation?
The Fugacity of Liq. Phase Species using Poynting Factor Correlation formula is defined as the function of saturated fugacity coefficient of a species, saturated pressure, volume of the liquid phase of a component, pressure, saturated pressure and temperature and is represented as fl = ϕsat*Psat*exp((Vl*(P-Psat))/([R]*T)) or Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature)). Saturated Fugacity Coefficient of Species is the ratio of the saturated fugacity of a species to the saturated pressure of a species, Saturated pressure is the pressure at which a given liquid and its vapour or a given solid and its vapour can co-exist in equilibrium, at a given temperature, Volume of Liquid Phase is the volume of a component in liquid phase, Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed & Temperature is the degree or intensity of heat present in a substance or object.
How to calculate Fugacity of Liq. Phase Species using Poynting Factor Correlation?
The Fugacity of Liq. Phase Species using Poynting Factor Correlation formula is defined as the function of saturated fugacity coefficient of a species, saturated pressure, volume of the liquid phase of a component, pressure, saturated pressure and temperature is calculated using Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*exp((Volume of Liquid Phase*(Pressure-Saturated Pressure))/([R]*Temperature)). To calculate Fugacity of Liq. Phase Species using Poynting Factor Correlation, you need Saturated Fugacity Coefficient of Species sat), Saturated Pressure (Psat), Volume of Liquid Phase (Vl), Pressure (P) & Temperature (T). With our tool, you need to enter the respective value for Saturated Fugacity Coefficient of Species, Saturated Pressure, Volume of Liquid Phase, Pressure & Temperature and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Fugacity of Liquid Phase Species?
In this formula, Fugacity of Liquid Phase Species uses Saturated Fugacity Coefficient of Species, Saturated Pressure, Volume of Liquid Phase, Pressure & Temperature. We can use 1 other way(s) to calculate the same, which is/are as follows -
  • Fugacity of Liquid Phase Species = Saturated Fugacity Coefficient of Species*Saturated Pressure*Poynting Factor
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