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EMF of Concentration Cell without Transference given Molalities and Activity Coefficient Calculator

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✖Temperature is the degree or intensity of heat present in a substance or object.ⓘ Temperature [T]			+10% -10%
✖The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.ⓘ Cathodic Electrolyte Molality [m₂]			+10% -10%
✖The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell.ⓘ Cathodic Activity Coefficient [γ₂]			+10% -10%
✖The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell.ⓘ Anodic Electrolyte Molality [m₁]			+10% -10%
✖The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.ⓘ Anodic Activity Coefficient [γ₁]			+10% -10%

✖The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.ⓘ EMF of Concentration Cell without Transference given Molalities and Activity Coefficient [EMF]

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EMF of Concentration Cell without Transference given Molalities and Activity Coefficient Solution

STEP 0: Pre-Calculation Summary

Formula Used

EMF of Cell = 2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient)))
EMF = 2*(([R]*T)/[Faraday])*(ln((m₂*γ₂)/(m₁*γ₁)))
This formula uses 2 Constants, 1 Functions, 6 Variables

Constants Used

[Faraday] - Faraday constant Value Taken As 96485.33212
[R] - Universal gas constant Value Taken As 8.31446261815324

Functions Used

ln - The natural logarithm, also known as the logarithm to the base e, is the inverse function of the natural exponential function., ln(Number)

Variables Used

EMF of Cell - (Measured in Volt) - The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
Cathodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.
Cathodic Activity Coefficient - The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell.
Anodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell.
Anodic Activity Coefficient - The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.

STEP 1: Convert Input(s) to Base Unit

Temperature: 85 Kelvin --> 85 Kelvin No Conversion Required
Cathodic Electrolyte Molality: 0.13 Mole per Kilogram --> 0.13 Mole per Kilogram No Conversion Required
Cathodic Activity Coefficient: 0.1 --> No Conversion Required
Anodic Electrolyte Molality: 0.4 Mole per Kilogram --> 0.4 Mole per Kilogram No Conversion Required
Anodic Activity Coefficient: 5.5 --> No Conversion Required

STEP 2: Evaluate Formula

Substituting Input Values in Formula

EMF = 2*(([R]*T)/[Faraday])*(ln((m₂*γ₂)/(m₁*γ₁))) --> 2*(([R]*85)/[Faraday])*(ln((0.13*0.1)/(0.4*5.5)))

Evaluating ... ...

EMF = -0.075170269787457

STEP 3: Convert Result to Output's Unit

-0.075170269787457 Volt --> No Conversion Required

FINAL ANSWER

-0.075170269787457 ≈ -0.07517 Volt <-- EMF of Cell

(Calculation completed in 00.008 seconds)

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K J Somaiya College of science (K J Somaiya), Mumbai

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< EMF of Concentration Cell Calculators

EMF of Concentration Cell without Transference given Molalities and Activity Coefficient

LaTeX Go EMF of Cell = 2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient)))

EMF of Concentration Cell without Transference given Concentration and Fugacity

LaTeX Go EMF of Cell = 2*(([R]*Temperature)/[Faraday])*ln((Cathodic Concentration*Cathodic Fugacity)/(Anodic Concentration*Anodic Fugacity))

EMF of Concentration Cell without Transference given Activities

LaTeX Go EMF of Cell = (([R]*Temperature)/[Faraday])*(ln(Cathodic Ionic Activity/Anodic Ionic Activity))

EMF of Due Cell

LaTeX Go EMF of Cell = Standard Reduction Potential of Cathode-Standard Oxidation Potential of Anode

EMF of Concentration Cell without Transference given Molalities and Activity Coefficient Formula

LaTeX Go

What is Concentration cell without transference?

A cell in which the transference of a substance from a system of high concentration to one at low concentration results in the production of electrical energy is called a concentration cell. It consists of two half cells having two identical electrodes and identical electrolytes but with different concentrations. EMF of this cell depends upon the difference of concentration. Concentration cell without transference is no direct transference of electrolyte but it occurs due to the result of the chemical reaction. Each electrode is reversible with respect to one of the ions of the electrolyte.

How to Calculate EMF of Concentration Cell without Transference given Molalities and Activity Coefficient?

EMF of Concentration Cell without Transference given Molalities and Activity Coefficient calculator uses EMF of Cell = 2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))) to calculate the EMF of Cell, The EMF of concentration cell without transference given molalities and activity coefficient formula is defined as relations with molality and activity coefficient of electrolyte present in cathode and anode half cell at a particular temperature. EMF of Cell is denoted by EMF symbol.

How to calculate EMF of Concentration Cell without Transference given Molalities and Activity Coefficient using this online calculator? To use this online calculator for EMF of Concentration Cell without Transference given Molalities and Activity Coefficient, enter Temperature (T), Cathodic Electrolyte Molality (m₂), Cathodic Activity Coefficient (γ₂), Anodic Electrolyte Molality (m₁) & Anodic Activity Coefficient (γ₁) and hit the calculate button. Here is how the EMF of Concentration Cell without Transference given Molalities and Activity Coefficient calculation can be explained with given input values -> -0.07517 = 2*(([R]*85)/[Faraday])*(ln((0.13*0.1)/(0.4*5.5))).

FAQ

What is EMF of Concentration Cell without Transference given Molalities and Activity Coefficient?

The EMF of concentration cell without transference given molalities and activity coefficient formula is defined as relations with molality and activity coefficient of electrolyte present in cathode and anode half cell at a particular temperature and is represented as EMF = 2*(([R]*T)/[Faraday])*(ln((m₂*γ₂)/(m₁*γ₁))) or EMF of Cell = 2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))). Temperature is the degree or intensity of heat present in a substance or object, The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell, The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell, The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell & The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.

How to calculate EMF of Concentration Cell without Transference given Molalities and Activity Coefficient?

The EMF of concentration cell without transference given molalities and activity coefficient formula is defined as relations with molality and activity coefficient of electrolyte present in cathode and anode half cell at a particular temperature is calculated using EMF of Cell = 2*(([R]*Temperature)/[Faraday])*(ln((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/(Anodic Electrolyte Molality*Anodic Activity Coefficient))). To calculate EMF of Concentration Cell without Transference given Molalities and Activity Coefficient, you need Temperature (T), Cathodic Electrolyte Molality (m₂), Cathodic Activity Coefficient (γ₂), Anodic Electrolyte Molality (m₁) & Anodic Activity Coefficient (γ₁). With our tool, you need to enter the respective value for Temperature, Cathodic Electrolyte Molality, Cathodic Activity Coefficient, Anodic Electrolyte Molality & Anodic Activity Coefficient and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.

How many ways are there to calculate EMF of Cell?

In this formula, EMF of Cell uses Temperature, Cathodic Electrolyte Molality, Cathodic Activity Coefficient, Anodic Electrolyte Molality & Anodic Activity Coefficient. We can use 3 other way(s) to calculate the same, which is/are as follows -

EMF of Cell = Standard Reduction Potential of Cathode-Standard Oxidation Potential of Anode
EMF of Cell = (([R]*Temperature)/[Faraday])*(ln(Cathodic Ionic Activity/Anodic Ionic Activity))
EMF of Cell = 2*(([R]*Temperature)/[Faraday])*ln((Cathodic Concentration*Cathodic Fugacity)/(Anodic Concentration*Anodic Fugacity))

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