Diffusion Current Solution

STEP 0: Pre-Calculation Summary
Formula Used
Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation)
Id = 607*(n)*(D)^(1/2)*(mr)^(2/3)*(t)^(1/6)*(c)
This formula uses 6 Variables
Variables Used
Diffusion Current for Ilkovic Equation - (Measured in Ampere) - Diffusion Current for Ilkovic Equation is defined as the actual diffusion of electroreducible ion from the bulk of the sample to the surface of the mercury droplet due to concentration gradient.
No. of Electrons for Ilkovic Equation - No. of Electrons for Ilkovic Equation is defined as the number of electrons exchanged in the electrode reaction.
Diffusion Coefficient for Ilkovic Equation - (Measured in Square Meter Per Second) - Diffusion Coefficient for Ilkovic Equation is defined as the diffusion coefficient of the polarizer in the medium.
Mass Flow Rate for Ilkovic Equation - (Measured in Kilogram per Second) - Mass Flow Rate for Ilkovic Equation is defined as the mass of liquid mercury passing per unit time.
Time for Dropping Mercury - (Measured in Second) - Time for Dropping Mercury is defined as the lifetime of the drop of mercury in the electrode.
Concentration for Ilkovic Equation - (Measured in Mole per Cubic Meter) - Concentration for Ilkovic Equation is defined as the concentration of the depolariser in the dropping mercury electrode.
STEP 1: Convert Input(s) to Base Unit
No. of Electrons for Ilkovic Equation: 2 --> No Conversion Required
Diffusion Coefficient for Ilkovic Equation: 6.9E-06 Square Centimeter Per Second --> 6.9E-10 Square Meter Per Second (Check conversion ​here)
Mass Flow Rate for Ilkovic Equation: 4 Milligram per Second --> 4E-06 Kilogram per Second (Check conversion ​here)
Time for Dropping Mercury: 4 Second --> 4 Second No Conversion Required
Concentration for Ilkovic Equation: 3 Millimole per Cubic Millimeter --> 3000000 Mole per Cubic Meter (Check conversion ​here)
STEP 2: Evaluate Formula
Substituting Input Values in Formula
Id = 607*(n)*(D)^(1/2)*(mr)^(2/3)*(t)^(1/6)*(c) --> 607*(2)*(6.9E-10)^(1/2)*(4E-06)^(2/3)*(4)^(1/6)*(3000000)
Evaluating ... ...
Id = 30.372542348209
STEP 3: Convert Result to Output's Unit
30.372542348209 Ampere -->30372542.348209 Microampere (Check conversion ​here)
FINAL ANSWER
30372542.348209 3E+7 Microampere <-- Diffusion Current for Ilkovic Equation
(Calculation completed in 00.008 seconds)

Credits

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Created by Ritacheta Sen
University of Calcutta (C.U), Kolkata
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National University of Judicial Science (NUJS), Kolkata
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Polarography Calculators

No of Electrons given Diffusion Current
​ LaTeX ​ Go No. of Electrons for Ilkovic Equation = Diffusion Current for Ilkovic Equation/(607*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation))
Diffusion Current
​ LaTeX ​ Go Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation)
Diffusion Coefficient given Diffusion Current
​ LaTeX ​ Go Diffusion Coefficient for Ilkovic Equation = (Diffusion Current for Ilkovic Equation/(607*(No. of Electrons for Ilkovic Equation)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation)))^2
Drop Lifetime given Diffusion Current
​ LaTeX ​ Go Time for Dropping Mercury = (Diffusion Current for Ilkovic Equation/(607*(No. of Electrons for Ilkovic Equation)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Concentration for Ilkovic Equation)))^6

Diffusion Current Formula

​LaTeX ​Go
Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation)
Id = 607*(n)*(D)^(1/2)*(mr)^(2/3)*(t)^(1/6)*(c)

What is the principle of polarography ?

Polarography is an electrochemical method of analysis based on the measurement of current flow resulting from the electrolysis of a solution at a polarisable microelectrode as a function of applied voltage. Polarography is based upon the principle that gradually increasing voltage is applied between two electrodes, one of which is polarisable (dropping mercury electrode) and other is non-polarisable and current flowing between the two electrodes is
recorded. A sigmoid shape current-voltage curve is obtained from which half wave potential as well as diffusion current is calculated. Diffusion current is used for determination of concentration of substance. Half wave potential is characteristic of every element.

How to Calculate Diffusion Current?

Diffusion Current calculator uses Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation) to calculate the Diffusion Current for Ilkovic Equation, The Diffusion Current formula is defined as the actual diffusion of electroreducible ion from the bulk of the sample to the surface of the mercury droplet due to concentration gradient. Diffusion Current for Ilkovic Equation is denoted by Id symbol.

How to calculate Diffusion Current using this online calculator? To use this online calculator for Diffusion Current, enter No. of Electrons for Ilkovic Equation (n), Diffusion Coefficient for Ilkovic Equation (D), Mass Flow Rate for Ilkovic Equation (mr), Time for Dropping Mercury (t) & Concentration for Ilkovic Equation (c) and hit the calculate button. Here is how the Diffusion Current calculation can be explained with given input values -> 3E+13 = 607*(2)*(6.9E-10)^(1/2)*(4E-06)^(2/3)*(4)^(1/6)*(3000000).

FAQ

What is Diffusion Current?
The Diffusion Current formula is defined as the actual diffusion of electroreducible ion from the bulk of the sample to the surface of the mercury droplet due to concentration gradient and is represented as Id = 607*(n)*(D)^(1/2)*(mr)^(2/3)*(t)^(1/6)*(c) or Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation). No. of Electrons for Ilkovic Equation is defined as the number of electrons exchanged in the electrode reaction, Diffusion Coefficient for Ilkovic Equation is defined as the diffusion coefficient of the polarizer in the medium, Mass Flow Rate for Ilkovic Equation is defined as the mass of liquid mercury passing per unit time, Time for Dropping Mercury is defined as the lifetime of the drop of mercury in the electrode & Concentration for Ilkovic Equation is defined as the concentration of the depolariser in the dropping mercury electrode.
How to calculate Diffusion Current?
The Diffusion Current formula is defined as the actual diffusion of electroreducible ion from the bulk of the sample to the surface of the mercury droplet due to concentration gradient is calculated using Diffusion Current for Ilkovic Equation = 607*(No. of Electrons for Ilkovic Equation)*(Diffusion Coefficient for Ilkovic Equation)^(1/2)*(Mass Flow Rate for Ilkovic Equation)^(2/3)*(Time for Dropping Mercury)^(1/6)*(Concentration for Ilkovic Equation). To calculate Diffusion Current, you need No. of Electrons for Ilkovic Equation (n), Diffusion Coefficient for Ilkovic Equation (D), Mass Flow Rate for Ilkovic Equation (mr), Time for Dropping Mercury (t) & Concentration for Ilkovic Equation (c). With our tool, you need to enter the respective value for No. of Electrons for Ilkovic Equation, Diffusion Coefficient for Ilkovic Equation, Mass Flow Rate for Ilkovic Equation, Time for Dropping Mercury & Concentration for Ilkovic Equation and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
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