B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient Solution

STEP 0: Pre-Calculation Summary
Formula Used
Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure
B1 = (Z1*Tr)/Pr
This formula uses 4 Variables
Variables Used
Pitzer Correlations Coefficient B(1) - Pitzer Correlations Coefficient B(1) is calculated from Abott equation. It's a function of reduced temperature.
Pitzer Correlations Coefficient Z(1) - Pitzer Correlations Coefficient Z(1) value is got from Lee-Kessler table. It depends on reduced temperature and reduced pressure.
Reduced Temperature - Reduced Temperature is the ratio of the actual temperature of the fluid to its critical temperature. It is dimensionless.
Reduced Pressure - Reduced Pressure is the ratio of the actual pressure of the fluid to its critical pressure. It is dimensionless.
STEP 1: Convert Input(s) to Base Unit
Pitzer Correlations Coefficient Z(1): 0.27 --> No Conversion Required
Reduced Temperature: 10 --> No Conversion Required
Reduced Pressure: 3.675E-05 --> No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
B1 = (Z1*Tr)/Pr --> (0.27*10)/3.675E-05
Evaluating ... ...
B1 = 73469.387755102
STEP 3: Convert Result to Output's Unit
73469.387755102 --> No Conversion Required
FINAL ANSWER
73469.387755102 73469.39 <-- Pitzer Correlations Coefficient B(1)
(Calculation completed in 00.004 seconds)

Credits

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Created by Shivam Sinha
National Institute Of Technology (NIT), Surathkal
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Verified by Pragati Jaju
College Of Engineering (COEP), Pune
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Equation of States Calculators

Acentric Factor using Pitzer Correlations for Compressibility Factor
​ LaTeX ​ Go Acentric Factor = (Compressibility Factor-Pitzer Correlations Coefficient Z(0))/Pitzer Correlations Coefficient Z(1)
Compressibility Factor using Pitzer Correlations for Compressibility Factor
​ LaTeX ​ Go Compressibility Factor = Pitzer Correlations Coefficient Z(0)+Acentric Factor*Pitzer Correlations Coefficient Z(1)
Reduced Temperature
​ LaTeX ​ Go Reduced Temperature = Temperature/Critical Temperature
Reduced Pressure
​ LaTeX ​ Go Reduced Pressure = Pressure/Critical Pressure

B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient Formula

​LaTeX ​Go
Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure
B1 = (Z1*Tr)/Pr

Why we use virial equation of state?

Since the perfect gas law is an imperfect description of a real gas, we can combine the perfect gas law and the compressibility factors of real gases to develop an equation to describe the isotherms of a real gas. This Equation is known as the Virial Equation of state, which expresses the deviation from ideality in terms of a power series in the density.
The actual behavior of fluids is often described with the virial equation:
PV = RT[1 + (B/V) + (C/(V^2)) + ...] ,
where,
B is the second virial coefficient,
C is called the third virial coefficient, etc.

in which the temperature-dependent constants for each gas are known as the virial coefficients. The second virial coefficient, B, has units of volume (L).

Why we modify the second virial coefficient to reduced second virial coefficient?

Since the tabular nature of the generalized compressibility-factor correlation is a disadvantage, but the complexity of the functions Z(0) and Z(1) precludes their accurate representation by simple equations. Nonetheless, we can give approximate analytical expression to these functions for a limited range of pressures. So we modify the second virial coefficient to reduced the second virial coefficient.

How to Calculate B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient?

B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient calculator uses Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure to calculate the Pitzer Correlations Coefficient B(1), The B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient formula is defined as the function of the Z(1), reduced pressure and the reduced temperature. Pitzer Correlations Coefficient B(1) is denoted by B1 symbol.

How to calculate B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient using this online calculator? To use this online calculator for B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient, enter Pitzer Correlations Coefficient Z(1) (Z1), Reduced Temperature (Tr) & Reduced Pressure (Pr) and hit the calculate button. Here is how the B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient calculation can be explained with given input values -> 73469.39 = (0.27*10)/3.675E-05.

FAQ

What is B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient?
The B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient formula is defined as the function of the Z(1), reduced pressure and the reduced temperature and is represented as B1 = (Z1*Tr)/Pr or Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure. Pitzer Correlations Coefficient Z(1) value is got from Lee-Kessler table. It depends on reduced temperature and reduced pressure, Reduced Temperature is the ratio of the actual temperature of the fluid to its critical temperature. It is dimensionless & Reduced Pressure is the ratio of the actual pressure of the fluid to its critical pressure. It is dimensionless.
How to calculate B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient?
The B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient formula is defined as the function of the Z(1), reduced pressure and the reduced temperature is calculated using Pitzer Correlations Coefficient B(1) = (Pitzer Correlations Coefficient Z(1)*Reduced Temperature)/Reduced Pressure. To calculate B(1) given Z(1) using Pitzer Correlations for Second Virial Coefficient, you need Pitzer Correlations Coefficient Z(1) (Z1), Reduced Temperature (Tr) & Reduced Pressure (Pr). With our tool, you need to enter the respective value for Pitzer Correlations Coefficient Z(1), Reduced Temperature & Reduced Pressure and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Pitzer Correlations Coefficient B(1)?
In this formula, Pitzer Correlations Coefficient B(1) uses Pitzer Correlations Coefficient Z(1), Reduced Temperature & Reduced Pressure. We can use 1 other way(s) to calculate the same, which is/are as follows -
  • Pitzer Correlations Coefficient B(1) = 0.139-0.172/(Reduced Temperature^4.2)
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